Fructose metabolism

DiNicolantonio JJ, O'Keefe JH, Lucan SC. Added fructose: a principal driver of type 2 diabetes mellitus and its consequences. Mayo Clin Proc. 2015 Mar;90(3):372–81. doi: 10.1016/j.mayocp.2014.12.019. PMID: 25639270.; Kolderup A, Svihus B. Fructose Metabolism and Relation to Atherosclerosis, Type 2 Diabetes, and Obesity. Journal of Nutrition and Metabolism. 2015;2015():1–12. doi: 10.1155/2015/823081.; van Buul VJ, Tappy L, Brouns FJPH. Misconceptions about fructose-containing sugars and their role in the obesity epidemic. Nutr. Res. Rev. 2014 Mar 25;27(1):119–30. doi: 10.1017/s0954422414000067.; Bray GA. Energy and Fructose From Beverages Sweetened With Sugar or High-Fructose Corn Syrup Pose a Health Risk for Some People. Advances in Nutrition. 2013 Mar;4(2):220–5. doi: 10.3945/an.112.002816.; Rippe JM, Angelopoulos TJ. Sucrose, High-Fructose Corn Syrup, and Fructose, Their Metabolism and Potential Health Effects: What Do We Really Know? Advances in Nutrition. 2013 Mar;4(2):236–45. doi: 10.3945/an.112.002824.; Oates PJ. Aldose reductase, still a compelling target for diabetic neuropathy. Curr Drug Targets. 2008 Jan;9(1):14–36. doi: 10.2174/138945008783431781. PMID: 18220710.; Mayes P. Intermediary metabolism of fructose. The American Journal of Clinical Nutrition. 1993 Nov;58(5):754S–765S. doi: 10.1093/ajcn/58.5.754s.; Sillero MAG, Sillero A, Sols A. Enzymes Involved in Fructose Metabolism in Liver and the Glyceraldehyde Metabolic Crossroads. European Journal of Biochemistry. 1969 Sep;10(2):345–50. doi: 10.1111/j.1432-1033.1969.tb00696.x.; HERS HG. [The mechanism of the formation of seminal fructose and fetal fructose]. Biochim Biophys Acta. 1960 Jan 01;37():127–38. doi: 10.1016/0006-3002(60)90086-x. PMID: 14401391.; HERS HG, KUSAKA T. [The metabolism of fructose-1-phosphate in the liver]. Biochim Biophys Acta. 1953 Jul;11(3):427–37. doi: 10.1016/0006-3002(53)90062-6. PMID: 13093749.

Metabolites

beta-D-Fructose

Formula: C6H12O6 (180.0633852)

CAS ID: 53188-23-1

D-Fructose

Formula: C6H12O6 (180.0633852)

CAS ID: 57-48-7

D-Glucose

Formula: C6H12O6 (180.0633852)

CAS ID: 50-99-7

D-Glyceraldehyde

Formula: C3H6O3 (90.0316926)

CAS ID: 453-17-8

D-Sorbitol

Formula: C6H14O6 (182.0790344)

CAS ID: 50-70-4

H+

Formula: H (1.0078246)

CAS ID: 12408-02-5

H2O

Formula: H2O (18.0105642)

CAS ID: 7732-18-5

Magnesium cation

Formula: Mg (23.98505)

CAS ID: 22537-22-0

Potassium cation

Formula: K (38.963708)

CAS ID: 24203-36-9

Zinc cation

Formula: Zn (63.929145)

CAS ID: 23713-49-7

NADPH(4-)

Formula: C21H26N7O17P3 (741.0598016)

CAS ID: 53-57-6

ATP(4-)

Formula: C10H12N5O13P3 (502.9644492)

CAS ID:

NAD(1-)

Formula: C21H26N7O14P2 (662.1012936000001)

CAS ID: 53-84-9

ADP(3-)

Formula: C10H12N5O10P2 (424.0059412)

CAS ID:

NADP(3-)

Formula: C21H25N7O17P3 (740.051977)

CAS ID: 53-59-8



Enzyme

EC Number name full name note
1.1.1.-
1.1.1.14 L-iditol 2-dehydrogenase L-iditol:NAD+ 2-oxidoreductase
1.1.1.21 aldose reductase alditol:NAD(P)+ 1-oxidoreductase
1.1.1.300 NADP-retinol dehydrogenase retinol:NADP+ oxidoreductase
1.1.1.372 D/L-glyceraldehyde reductase glycerol:NADP+ oxidoreductase (D/L-glyceraldehyde-forming)
1.1.1.54 allyl-alcohol dehydrogenase allyl-alcohol:NADP+ oxidoreductase
1.1.1.9 D-xylulose reductase xylitol:NAD+ 2-oxidoreductase (D-xylulose-forming)
1.2.1.19 aminobutyraldehyde dehydrogenase 4-aminobutanal:NAD+ 1-oxidoreductase
1.2.1.28 benzaldehyde dehydrogenase (NAD+) benzaldehyde:NAD+ oxidoreductase
1.2.1.3 aldehyde dehydrogenase (NAD+) aldehyde:NAD+ oxidoreductase
1.2.1.36 retinal dehydrogenase retinal:NAD+ oxidoreductase
2.7.1.28 triokinase ATP:D-glyceraldehyde 3-phosphotransferase
2.7.1.29 glycerone kinase ATP:glycerone phosphotransferase
2.7.1.3 ketohexokinase ATP:D-fructose 1-phosphotransferase
2.7.1.31 glycerate 3-kinase ATP:D-glycerate 3-phosphotransferase
4.1.2.13 fructose-bisphosphate aldolase D-fructose-1,6-bisphosphate D-glyceraldehyde-3-phosphate-lyase (glycerone-phosphate-forming)
4.6.1.15 FAD-AMP lyase (cyclizing) FAD AMP-lyase (riboflavin-cyclic-4',5'-phosphate-forming)


Proteins

Protein ID name full name