Rhea:RHEA:17259
Published in: Falkenhagen, H. and Stockligt, J. Enzymatic biosynthesis of vomilenine, a key intermediate of the ajmaline pathway, catalysed by a novel cytochrome P-450-dependent enzyme from plant cell cultures of Rauwolfia serpentina. Z. Naturforsch. C: Biosci. 50 (1995) 45–53. DOI:doi.org/10.3987/com-95-7122
vomilenine + oxidized [NADPH—hemoprotein reductase] + H2O + H+ => vinorine + reduced [NADPH—hemoprotein reductase] + O2
= Vomilenine[C21H22N2O3] + [] + H2O[H2O] + H+[H] + Vinorine[C21H22N2O2] + [] + Oxygen[O2]
DB Links
- EC Number: 1.14.14.104
- Rhea: RHEA:17259
Alias
- [Rhea:RHEA:17258] vinorine + reduced [NADPH—hemoprotein reductase] + O2 => vomilenine + oxidized [NADPH—hemoprotein reductase] + H2O + H+
- [Rhea:RHEA:17259] vomilenine + oxidized [NADPH—hemoprotein reductase] + H2O + H+ => vinorine + reduced [NADPH—hemoprotein reductase] + O2
- [Rhea:RHEA:17260] vinorine + reduced [NADPH—hemoprotein reductase] + O2 <=> vomilenine + oxidized [NADPH—hemoprotein reductase] + H2O + H+
Metabolites
Substrates
| metabolite | compartment | Structure |
|---|
Products
| metabolite | compartment | Structure |
|---|---|---|
| Vomilenine Formula: C21H22N2O3 |
Cytoplasm | |
Formula: |
Cytoplasm | |
| H2O Formula: H2O |
Cytoplasm | |
| H+ Formula: H |
Cytoplasm | |
| Vinorine Formula: C21H22N2O2 |
Cytoplasm | |
Formula: |
Cytoplasm | |
| Oxygen Formula: O2 |
Cytoplasm |