phenolic malonylglucosides biosynthesis

Taguchi G, Ubukata T, Nozue H, Kobayashi Y, Takahi M, Yamamoto H, Hayashida N. Malonylation is a key reaction in the metabolism of xenobiotic phenolic glucosides in Arabidopsis and tobacco. Plant J. 2010 Sep;63(6):1031–41. doi: 10.1111/j.1365-313x.2010.04298.x. PMID: 20626660.; Taguchi G, Shitchi Y, Shirasawa S, Yamamoto H, Hayashida N. Molecular cloning, characterization, and downregulation of an acyltransferase that catalyzes the malonylation of flavonoid and naphthol glucosides in tobacco cells. Plant J. 2005 May;42(4):481–91. doi: 10.1111/j.1365-313x.2005.02387.x. PMID: 15860007.

Metabolites

1-Naphthol

Formula: C10H8O (144.0575118)

CAS ID: 90-15-3

2-Naphthol

Formula: C10H8O (144.0575118)

CAS ID: 135-19-3

H+

Formula: H (1.0078246)

CAS ID: 12408-02-5

UDP(3-)

Formula: C9H11N2O12P2 (400.9787246)

CAS ID: 86527-70-0



Enzyme

EC Number name full name note
2.3.1.-
2.3.1.116 flavonol-3-O-beta-glucoside O-malonyltransferase malonyl-CoA:flavonol-3-O-beta-D-glucoside 6''-O-malonyltransferase


Proteins

Protein ID name full name