geraniol and geranial biosynthesis

Ito M, Honda G. Geraniol synthases from perilla and their taxonomical significance. Phytochemistry. 2007 Feb;68(4):446–53. doi: 10.1016/j.phytochem.2006.11.006. PMID: 17187833.

Metabolites

cis-Citral

Formula: C10H16O (152.12010859999998)

CAS ID: 106-26-3

Diphosphate

Formula: H4P2O7 (177.9432294)

CAS ID: 2466-09-3

Geranial

Formula: C10H16O (152.12010859999998)

CAS ID: 141-27-5

Geraniol

Formula: C10H18O (154.1357578)

CAS ID: 106-24-1

H+

Formula: H (1.0078246)

CAS ID: 12408-02-5

H2O

Formula: H2O (18.0105642)

CAS ID: 7732-18-5

Magnesium cation

Formula: Mg (23.98505)

CAS ID: 22537-22-0

Manganese(2+)

Formula: Mn (54.938046)

CAS ID: 7439-96-5

Zinc cation

Formula: Zn (63.929145)

CAS ID: 23713-49-7

NADPH(4-)

Formula: C21H26N7O17P3 (741.0598016)

CAS ID: 53-57-6

NADP(3-)

Formula: C21H25N7O17P3 (740.051977)

CAS ID: 53-59-8



Enzyme

EC Number name full name note
1.1.1.183 geraniol dehydrogenase (NADP+) geraniol:NADP+ oxidoreductase
1.1.1.195 cinnamyl-alcohol dehydrogenase cinnamyl-alcohol:NADP+ oxidoreductase
3.1.7.11 geranyl diphosphate diphosphatase geranyl-diphosphate diphosphohydrolase
3.1.7.6 farnesyl diphosphatase (2E,6E)-farnesyl-diphosphate diphosphohydrolase
4.2.3.19 ent-kaurene synthase ent-copalyl-diphosphate diphosphate-lyase (cyclizing, ent-kaurene-forming)
4.2.3.26 R-linalool synthase geranyl-diphosphate diphosphate-lyase [(3R)-linalool-forming]
4.2.3.47 beta-farnesene synthase (2E,6E)-farnesyl-diphosphate diphosphate-lyase [(E)-beta-farnesene-forming]
4.2.3.49 (3R,6E)-nerolidol synthase (2E,6E)-farnesyl-diphosphate diphosphate-lyase [(3R,6E)-nerolidol-forming]


Proteins

Protein ID name full name